In-depth

EV Batteries – LFP vs NMC, Total vs Usable

The EV battery (sometimes called traction or high-voltage battery) is the most expensive component in the vehicle.

January 31, 2024       14 min read

The battery’s capacity is measured in kilowatt-hours (kWh) and indicates the amount of electricity available to the car.

Total or usable?

Manufacturers list battery capacity as either gross (total) or net (usable).

This is confusing as some makers don’t state which is which.

  • Gross (total) – the complete capacity.
  • Net (usable) – how much capacity the vehicle is allowed to access.

Why the difference?

To maintain lithium-ion batteries in good condition, they should not be allowed to be empty (0% charge) or full (100% charge).

The gross capacity is not a particularly insightful spec, so measuring usable capacity is best.

Total vs Usable Battery Capacity

How does this work? And why?

The vehicle maintains an artificial buffer (around 2-5% of total capacity) that prevents the driver from completely draining or fully charging.

Sophisticated electronics manage this ‘buffer’ called the Battery Management System (BMS).

Even though your dashboard might say 100% – there is still some room in the battery.

When your battery ‘seems’ empty, more electricity remains. Most EVs will go into ‘snail mode’ to prevent the complete draining of the battery. Snail mode severely restricts speed to avoid stranding.

What are LFP, NMC, and NCA batteries?

Almost all EV batteries are lithium-ion, and different lithium-ion chemistries are named after their elements.

Common battery chemistries:

  • LMO – Lithium Manganese Oxide (LiMn2O4) — (used in early Nissan Leaf)
  • NMC – Lithium Nickel Manganese Cobalt Oxide (LiNiMnCoO2) — (used in later Nissan Leaf)
  • NCA – Lithium Nickel Cobalt Aluminum Oxide (LiNiCoAlO2) — (used in Tesla Model S and X)
  • LFP – Lithium Iron Phosphate (LiFePO4) — (used in some Teslas, BYD, and more).

✅ LFP Pros

  • Longer lifespan (slower degradation)
  • Lower cost
  • Safer (lower risk of thermal runaway)
  • No conflict materials (cobalt)

❌ LFP Cons

  • Less energy dense (shorter range for same size battery).
  • Less performant
  • Slower charging in cold temperatures

✅ NMC Pros

  • More energy dense (longer range for same size battery).
  • More power
  • Charges faster.

❌ NMC Cons

  • More expensive
  • Less durable
  • Conflict materials (cobalt)

LFP is more tolerant of full-charge conditions (i.e., can be charged weekly to 100%) and tends to be found in shorter-range EVs.

However, battery technology is improving. The new M3P chemistry from CATL offers a 15-20% improvement in energy density over the current LFP.

Which EVs use LFP batteries?

VehicleBatteryWLTP RangePrice
BYD Atto 3 50 kWh345 km$54,990
BYD Atto 3 Extended 60.5 kWh420 km$57,990
BYD Dolphin 44.9 kWh340 km$47,990
BYD Dolphin Extended 60.5 kWh427 km$53,990
BYD Seal Dynamic 61.4 kWh460 km$62,990
BYD Seal Performance 82.6 kWh520 km$83,990
BYD Seal Premium 82.6 kWh570 km$72,990
GWM Ora 45.4 kWh310 km$42,990
MG 4 Excite 51 50.8 kWh350 km$46,990
MG ZS EV 49 kWh320 km$50,990
Tesla Model 3 60.9 kWh513 km$65,900
Tesla Model 3 (2019-2023) Used60 kWh491 km$44k+
Tesla Model Y 60 kWh455 km$67,900

Not all Teslas have LFP. To tell if you have an LFP battery in a Tesla, open the Charging menu on the Tesla app. If you can set the limit to 100%, you have an LFP battery. Tesla also recommends:

  • “To maintain battery health, keep the charge limit at 100% and charge fully once per week.”

What makes EV batteries lose their capacity and why?

Lithium-ion batteries slowly lose their capacity due to two reasons:

  1. Calendar aging (a baseline level of degradation).
  2. How they are used.

How use causes wear

  1. Heat
    Early Nissan Leafs showed that without a cooling system, EV batteries degrade faster when heated.

    Newer EVs have active cooling systems. However, batteries left sitting in hot temperatures will degrade more quickly (heat speeds up the chemical reactions in a battery).
  2. Fast Charging
    The process of charging moves lithium ions and electrons around in the cells. Using a higher voltage results in the process happening more quickly and with more force, which can generate a lot of heat and stress the battery materials.
    UPDATE: This is improving. Research from Recurrent shows no difference between frequently DC fast-charged EVs and those rarely fast-charged (focusing on Tesla vehicles). This is due to the increasing sophistication of Battery Management Systems (BMS) that can manage the charging curve to minimise undue stress on the battery.
  3. Depth of Discharge
    Depth of discharge is how much power you use between charges.

    Battery cells last longer when the depth of discharge is small. Frequent, small charges are better for the battery than one large charge (note that LFP batteries are the least sensitive to depth of discharge issues).

Just how bad is degradation?

Early Nissan Leafs suffered the worst degradation.

Data from FliptheFleet shows that 8-9-year-old Leafs have lost about 23% of capacity (about 2.6% per year). These cars have some of the earliest battery technology of the modern EV.

If a modern EV with 450 km lost 1% per year, then after 15 years, it would still have a range of 380 km.

How do I keep the battery in top condition?

If you are looking to maintain maximum value, the following is the best practice:

  • Keep charge between 20% and 80% (note does not apply to LFP batteries).
  • Only charge to 100% when making a long trip, preferably just before you leave.
  • Keep the vehicle in the shade if you are in a hot climate.
  • Charge little and often
    Rather than running the car down to 10%, then right up again, charge each day (regular top-ups). There is extensive research on this (see references), and this may be the best you can do.
  • Drive the car!
    There doesn’t seem to be a correlation between the number of km travelled and the battery’s state of health.

Research comparing batteries (after 2,000 cycles) with different charging routines found:

  • With 80% depth of discharge: 85% capacity left.
  • With 50% depth of discharge: 90% capacity left.

Why would I buy an EV if the battery wears out?

It’s a valid question.

  • Battery technology is rapidly improving
    Some more recent EVs (such as the Hyundai Kona or IONIQ) show very little degradation after 4-5 years (and counting). The next generation can be expected to be even better.
  • Battery second-life use and recycling are also evolving fast
    See more in the Nissan Leaf battery upgrade guide.
  • All new EVs offer a 7-8 year battery warranty
  • Even with a replacement battery, the Total Cost of Ownership of the EV may still be better than a combustion car. Consider that savings from petrol could be $3000-5000 per year.

So how to know the value of an EV?

Battery degradation complicates value. Why buy an old secondhand EV for $8,000 only to replace a battery for $10,000 a few years later?

EVs are new technology, and we are learning that the value of an older vehicle is defined by its battery. We’re also learning that an EV is not a direct equivalent of a combustion car.

Older cell phones had batteries that required a weekly charge. Yet we’ve learned to accept powerful smartphones that require charging every day.

Do EVs have 12-volt batteries?

Yes. They use 12-volt batteries to power systems (the head unit, dashboard, etc.) when the vehicle is not started. These batteries eventually need replacing, just like in a combustion car.

What is the risk of a battery fire?

An EV battery has a 0.0012% chance of catching fire (compared with a 0.1% chance of a combustion car catching fire – source).

However, battery fires do happen and burn much hotter than combustion vehicle fires.

What causes an EV battery to catch fire?

A thermal runaway process occurs when a battery cell short-circuits and heats uncontrollably.

EV traction batteries are made up of cells joined together in modules. Modules are wired together to form the overall battery pack.

If one cell is severely damaged, intense heat can spread to other cells.

Thermal runaway fires are harder to put out and require special treatment by the fire service.

See more at www.evfiresafe.com

What is the environmental cost of EV battery production?

The production of lithium-ion batteries is a mining-intensive process.

  • Mining is mostly powered by fossil fuels.
  • Battery production (most of which takes place in China) is also mostly powered by fossil fuels.

Carbon emissions from EV batteries

It’s difficult to put an exact CO2 emission figure on a battery due to the variety of materials and production facilities.

One of the most commonly cited sources (2019 ref):

CO2 emissions on battery production:

61-106 kg CO2-eq/kWh

Example: 60 kWh battery produces 3.6-6.4 tonnes of CO2

This environmental burden can be lowered by consumers buying efficient EVs. Ironically mining emissions can be lowered by more mining vehicles going electric.

For example, the BMW iX M60 has a 112 kWh battery (range of 566 km), and the Hyundai Kona has a 67.5 kWh battery (range of 484 km). The M60 has double the carbon emissions due to its battery size – but just 80 km extra range.

How is this better than a petrol or diesel car?

As the factories that produce batteries move to more sustainable energy sources, the carbon cost of lithium-ion batteries will lower.

Although BEVs have elevated production phase emissions, these are offset by decreased emissions during the use phase.

The extent of this offset is greater with a greener grid. New Zealand has a high amount of renewable electricity production, meaning low carbon emissions during the use phase of the EV.

Status 🙄: EV emissions are lower than petrol or diesel, but room for improvement.

Lithium mining

The majority of lithium comes from Australia and Chile. Every mining process comes with a cost to the ecosystem, and the future lithium requirements are massive.

This can be mitigated by

  • Creating smaller, highly efficient EVs.
  • Maximum battery recycling.
  • Battery EVs are part of a larger transportation solution that includes mass transit, cycle paths, and pedestrian-friendly paths.

Does cobalt mining use child labour?

Cobalt is a rare, poisonous metal found in many lithium-ion batteries. It is expensive, heavy, and connected to unethical mining practices, big changes in price and an unstable supply chain.

Yes, children routinely work in hazardous mines, including cobalt mines. The ILO strives to reduce the number of children in these mines. Note that the Congo is not the only major supplier of Cobalt – Indonesia is fast becoming a significant source.

You probably had cobalt in all your mobile phones, laptops, and almost every other battery power device you’ve owned.

EV batteries also contain cobalt; however, this is changing.

BYD EVs and newer Tesla Model 3 and MG ZS EV models now use Lithium Iron Phosphate batteries (LiFePO 4 or LFP). Cobalt-free LFP batteries are increasingly becoming the battery of choice.

Status 🙁📈: Not great, but improving.

Battery reuse and recycling

A product stewardship program for large batteries is currently undergoing accreditation in NZ. This is spearheaded by the Battery Industry Group.

The idea is to have legitimate reuse and end-of-life processes – using a ‘battery passport’ allowing complete battery tracking.

A stewardship fee would be added to the cost of the vehicle at the import stage (determined by the weight of the battery).

US-based Redwood Materials completed its pilot in March 2023, claiming a 95% recovery rate of minerals from batteries. US-based Ascend Elements also has the capacity for large-scale recycling.

Li-cycle in the US also has a 95% recovery rate – see how they process an entire EV battery.

Status 🤔: Good things are in the pipeline, but there’s much to do.

References

  1. Ameli, M. T., & Ameli, A. (2021). Electric vehicles as means of energy storage: participation in ancillary services markets. In Energy Storage in Energy Markets (pp. 235-249). Academic Press. Link
  2. Preger, Y., Barkholtz, H. M., Fresquez, A., Campbell, D. L., Juba, B. W., Romàn-Kustas, J., … & Chalamala, B. (2020). Degradation of commercial lithium-ion cells as a function of chemistry and cycling conditions. Journal of The Electrochemical Society, 167(12), 120532. Link
  3. Xu, B., Oudalov, A., Ulbig, A., Andersson, G., & Kirschen, D. S. (2016). Modeling of lithium-ion battery degradation for cell life assessment. IEEE Transactions on Smart Grid, 9(2), 1131-1140. Link
  4. Emilsson, E., & Dahllöf, L. (2019). Lithium-ion vehicle battery production-status 2019 on energy use, CO2 emissions, use of metals, products environmental footprint, and recycling.
  5. Emilsson, E., & Dahllöf, L. (2019). Lithium-ion vehicle battery production-status 2019 on energy use, CO2 emissions, use of metals, products environmental footprint, and recycling.
  6. Xia, X., & Li, P. (2022). A review of the life cycle assessment of electric vehicles: Considering the influence of batteries. Science of The Total Environment, 152870. Link
  7. Andersson, Ö., & Börjesson, P. (2021). The greenhouse gas emissions of an electrified vehicle combined with renewable fuels: Life cycle assessment and policy implications. Applied Energy, 289, 116621.
  8. Global Battery Alliance Rulebook (2022) – A master document outlining everything about battery production link.
  9. Battery University
  10. EVFireSafe (Australian data on EV fires).
  11. Charted: Lithium Production. VisualCapitalist.